Dimethyl sulfide 甲硫醚

规格: 99%, SpcDry, Water≤50 ppm (by K.F.), SpcSeal
CAS: 75-18-3
产品编号: H55900
MDL: MFCD00008562
品牌: INFI
Chemical NameDimethyl sulfide
Synonym (CH3)2S 2-Thiapropane 2-Thiapropane; Methylsulphide; Methylthiomethane; Thiobismethane; Thiopropane; DMS; Methyl thioether 2-thiapropane DIMETHYL DISULFIDE DIMETHYL SULFIDE DIMETHYSULFIDE DMS DMS 甲硫醚 Dimethyl monosulfide Dimethyl sulphide Dimethylsulfid Exact-S FEMA 2746 ME2S METHYL SULFIDE Me2S Methane, thiobis- Methyl monosulfide Methyl sulfide Methylthiomethane Thiobis(methane) methane, thiobis- thiobismethane {} {} {} {} {} {} {} {} {Chemica 二甲基硫 二甲基硫醚,二甲硫,二甲基硫 二甲基硫醚10%溶液 二甲硫 二甲硫醚 甲基硫化物 甲硫醚 硫化二甲基
CAS Number75-18-3
EC Number200-846-2
Beilstein Registry Number1696847
MDL NumberMFCD00008562
PubChem Substance ID87572490
Reaxys-RN1696847
Merck Number6123
Chemical Name Translation二甲硫醚
Wiswesser Line Notation1S1
LabNetwork Molecule IDLN00164486
InChIInChI=1S/C2H6S/c1-3-2/h1-2H3
GHS Symbol
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 3700 mg/kg
TOXIC EFFECTS :
   Behavioral - changes in motor activity (specific assay)
   Behavioral - antipsychotic
   Nutritional and Gross Metabolic - other changes
REFERENCE :
   FC

TY

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Mammal - species unspecified
DOSE/DURATION           : 1950 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 16(6),46,1972

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 17,365,1979

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 8 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IJRBA3 International Journal of Radiation Biology and Related Studies in
   Physics, Chemistry and Medicine.  (Taylor & Francis Inc., 242 Cherry St.,
   Philadelphia, PA 19106)  V.1-    1959-  Volume(issue)/page/year: 3,41,1961

TYPE OF TEST            : LD50 - Leth

WGK Germany1
Hazard Codes 3 F
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H319 Causes serious eye irritation 严重刺激眼睛
    Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US)
    RTECSPV5075000
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241+P242+P243
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P303+P361+P353
    • P305+P351+P338
    • P305+P351+P338+P310
    • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
    • P370+P378
    • P403+P235
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S29 Do not empty into drains 不要排入下水道；
      • S33 Take precautionary measures against static discharges 对静电采取预防措施；
      • S36/39 Wear suitable protective clothing and eye/face protection 穿戴适当的防护服和眼睛/面保护；
      • S7 Keep container tightly closed 保存在严格密闭容器中；
      • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R22 Harmful if swallowed 吞咽有害
        • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
        • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
          UN Number 1164
          Packing GroupII
          Storage condition 密封阴凉保存。 储存温度2-8℃ 2-8°C 密封阴凉保存。夏天冰袋运输。
          Hazard Class3
          Warnings 危化品目录(2015)
        • 气相色谱分析标准。有机合成。溶剂。城市煤气赋臭剂。涂料脱膜剂。电池低温防腐剂。药物渗透剂。农药制备。
        • {ALD} Merck: 14,6123
        • {uni_hamburg} Short: II/19b
        • {uni_hamburg} Short: II/14a
        • {ALD} Merck: 14,6123
        • Beilstein:1,288
          • 75-18-3 H55900 Dimethyl sulfide 甲硫醚

          化学属性

          Mol. FormulaC2H6S
          Mol. Weight62.13
          Density0.846
          Refractive index1.4330 to 1.4370
          Boiling Point 38
          Melting Point-98
          Flash Point-34°C(lit.)
          TSCAYes
          Autoignition Point402 °F
          Vapor Density2.1 (vs air)
          Vapor Pressure26.24 psi ( 55 °C)
          Solubility不溶于水，溶于乙醇、乙醚等多数有机溶剂。
          Density0.846
          Mol. FormulaC2H6S
          Mol. Weight62
          Density0.826
          Mol. FormulaC2H6S
          Mol. Weight62.00