N-Phenyl-bis(trifluoromethanesulfonimide) N-苯基双(三氟甲烷磺酰)亚胺

规格: 95%
CAS: 37595-74-7
产品编号: H81905
MDL: MFCD00000404
品牌: INFI
Chemical Name1,1,1-Trifluoro-N-phenyl-N-((trifluoromethyl)sulfonyl)methanesulfonamide
CAS Number37595-74-7
Alfabeta NamePHENYLTRIFLUOROMETHANESULFONIMIDE N-
MDL NumberMFCD00000404
Synonym 1,1,1-Trifluoro-N-phenyl-N-(trifluoromethylsulfonyl)methanesulfonamide {SNA} 1,1,1-三氟-N-苯基-N-[(三氟甲基)磺酰基]甲磺酰胺 N,N-双(三氟甲磺酰基)苯胺 N-苯基-三氟甲磺酰亚胺 N-苯基双(三氟甲磺酰)亚胺 NSC 240874 N,N-Bis(trifluoromethanesulfonyl)aniline N,N-Bis(trifluoromethylsulfonyl)aniline N-Phenyl-trifluoromethanesulfonimide Phenyl triflimide 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide N,N-Bis(trifluoromethylsulfonyl)aniline, N-Phenyl-trifluoromethanesulfonimide Phenyl triflimide 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide N,N-Bis(trifluoromethylsulfonyl)aniline\u000a \u000a N-Phenyl-trifluoromethanesulfonimide\u000a \u000a Phenyl triflimide\u000a \u000a 1,1,1-Trifluoro-N-phenyl-N-[(trifluoromethyl)sulfonyl]methanesulfonamide N,N-双(三氟甲磺酰基)苯胺 N,N－双(三氟甲磺酰基)苯胺 N-苯基-三氟甲磺酰亚胺 N-苯基双(三氟甲烷磺酸亚胺) N-苯基对(三氟甲磺酰亚胺) NSC 240874
PubChem Substance ID87575352
Beilstein Registry Number1269141
EC Number250-023-7
Reaxys-RN1269141
Chemical Name TranslationN-苯基双(三氟甲烷磺酰)亚胺
LabNetwork Molecule IDLN00008442
InChIInChI=1S/C8H5F6NO4S2/c9-7(10,11)20(16,17)15(6-4-2-1-3-5-6)21(18,19)8(12,13)14/h1-5H
Canonical SMILESO=S(N(C1=CC=CC=C1)S(C(F)(F)F)(=O)=O)(C(F)(F)F)=O
GHS Symbol
Warnings IRRITANT
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    Hazard statements
    • H315 Causes skin irritation 会刺激皮肤
    • H319 Causes serious eye irritation 严重刺激眼睛
    • H335 May cause respiratory irritation 可能导致呼吸道刺激
      Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
      Signal word Warning
      Safety Statements
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
      • S37 Wear suitable gloves 戴适当手套；
        Risk Statements
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          Storage condition Moisture Sensitive Store at room temperature 对湿度敏感，密封保存
          Hazard Codes Xi
        • 三氟甲基磺酰化(Triflating)试剂。
        • {ALF} Convenient reagent for preparation of triflates of phenols and amines: Tetrahedron Lett., 4607 (1973); Org. Lett., 4, 1231 (2002); or of enol triflates from carbonyl compounds: Tetrahedron Lett., 24, 979 (1983); J. Org. Chem., 51, 277 (1986). For discussion of the reactivity of triflates, see Trifluoromethanesulfonic anhydride, A11767.
          • 37595-74-7 H81905 N-Phenyl-bis(trifluoromethanesulfonimide) N-苯基双(三氟甲烷磺酰)亚胺

          化学属性

          Mol. FormulaC8H5F6NO4S2
          Mol. Weight357.25
          Melting Point100-102°C
          TSCANo
          Density1.766
          Stability对湿度敏感
          Boiling Point305.3°C at 760 mmHg