Ethynyltrimethylsilane 三甲基硅乙炔

规格: 97%
CAS: 1066-54-2
产品编号: H83632
MDL: MFCD00008569
品牌: INFI
Chemical NameEthynyltrimethylsilane
CAS Number1066-54-2
Alfabeta NameTRIMETHYLSILYLACETYLENE ()
MDL NumberMFCD00008569
Synonym (TRIMETHYLSILYL)ACETYLENE, 98+% (Trimethylsilanyl)acetylene {uni_hamburg} (Trimethylsilyl)-acetylen (Trimethylsilyl)ethyne (三甲基甲硅烷基)乙炔 (三甲基硅烷基)乙炔 1-Trimethylsilylethyne Acetylene, trimethylsilyl- Eth Ethinyl-trimethylsilan Ethyne,-trimethylsilyl Ethynyl-trimethyl-silane Ethynyltrimethylsilane Ethynyltrimethylsilane~TMS acetylene Silane, trimethyl-, ethynyl- Silane,ethynyltrimethyl- TRIMETHYLSILYLACETYLENE Trimethylethynylsilane Trimethylsilanylethyne Trimethylsilylacetylene,min.97% ethynyltrimethyl-silan 三甲基乙炔基硅 三甲基乙炔基硅, 三甲基硅基乙炔 三甲基乙炔基硅; 三甲基硅基乙炔 三甲基乙炔基硅;三甲基硅基乙炔;乙炔基三甲基硅烷;三甲基硅乙炔;
PubChem Substance ID87577015
Beilstein Registry Number906752
EC Number213-919-9
Reaxys-RN906752
Chemical Name Translation三甲基硅基乙炔
InChIKeyCWMFRHBXRUITQE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00117256
InChIInChI=1S/C5H10Si/c1-5-6(2,3)4/h1H,2-4H3
Canonical SMILESC[Si](C)(C#C)C
GHS Symbol
Warnings IRRITANT, KEEP COLD, FLAMMABLE
WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
    Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US)
    Hazard Codes 3 F;Xi
    Precautionary statements
    • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
    • P233 Keep container tightly closed. ?保持容器密闭。
    • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
    • P241+P242+P243
    • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
    • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
    • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
    • P302+P352+P332+P313+P362+P364
    • P303+P361+P353
    • P305+P351+P338
    • P305+P351+P338+P337+P313
    • P332+P313
    • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
    • P370+P378
    • P403+P235
    • P501 Dispose of contents/container to..… 处理内容物/容器.....
      Signal word Danger
      Safety Statements
      • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
      • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
      • S29 Do not empty into drains 不要排入下水道；
      • S33 Take precautionary measures against static discharges 对静电采取预防措施；
      • S36 Wear suitable protective clothing 穿戴适当的防护服；
      • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
        Risk Statements
        • R11 Highly flammable 非常易燃
        • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
          UN Number 1993 UN 1993 3/PG 2
          Packing GroupII
          Storage condition 2-8°C Store at room temperature 低温，要绝对密封 储存温度2-8℃,充氩保存
          Hazard Class3
        • Ethynyltrimethylsilane was used in:
        • ? microwave-assisted, one-pot, three-step Sonogashira cross-coupling-desilylation-cycloaddition reaction for the preparation of 1,4-disubstituted 1,2,3-triazoles
        • synthesis of poly(ethynyltrimethylsilane) containing Pd (II) coordination sites
        • pyrazole synthesis via 1,3-dipolar cycloaddition of diazo compounds to acetylenes
        • {ALD} Beilstein: 4,IV,3937
        • {ALF} For the synthesis of iodoalkenes by radical addition of perfluoroalkyl iodides, see: J. Org. Chem., 47, 2251 (1982).
        • {uni_hamburg} Short: II/24A
        • {ALF} Pd catalyzed coupling with aryl bromides or iodides gives aryl TMS alkynes, from which the TMS group is readily cleaved by K2CO3 in MeOH: Synthesis, 627 (1980); J. Org. Chem., 46, 2280 (1981). Coupling with 1-bromo-2-nitrobenzene or ethyl 2-bromocarbanilate gives indole precursors. Other terminal alkynes lead to 2-substituted indoles: Heterocycles, 24, 31 (1986):
        • {ALF} Cross-coupling with aryl halides can also be catalyzed by Pd-C in the presence of Ph3P, CuI and Et3N: Synth. Commun., 20, 2059 (1990); for an example, see 2-Bromonaphthalene, A15300. Pd catalyzed coupling with quinolinol and isoquinolinol triflates has also been reported: Tetrahedron, 51, 3737 (1995). For coupling with vinyl halides catalyzed by Tetrakis(triphenyl­phosphine)­palladium(0)­, 10548 in the presence of CuI as an example of a route to enynes, see: Tetrahedron Lett., 30, 6997 (1989); Org. Synth. Coll., 9, 117 (1998). CuCl-TMEDA catalyzed oxidative (Hay) coupling gives bis(TMS)-1,3-butadiyne: Org. Synth. Coll., 8, 63 (1993).
          • 1066-54-2 H83632 Ethynyltrimethylsilane 三甲基硅乙炔

          化学属性

          Mol. FormulaC5H10Si
          Mol. Weight98.22
          Boiling Point52-53°C at 760 mmHg
          TSCAT
          Refractive index1.3890 to 1.3910
          Density0.695
          Flash Point-34°C
          Vapor Pressure4.18 psi ( 20 °C)
          Solubility起反应
          Stability对空气和湿度敏感
          Melting Point>0°C