Potassium permanganate, solution 0,2 mol/l (1 N) 高锰酸钾滴定液,0.2mol/l

规格: solution 0,2 mol/l (1 N)
CAS: 7722-64-7
产品编号: PO03351000
MDL: MFCD00011364
品牌: Scharlab
Chemical NamePotassiumPermanganate
MDL NumberMFCD00011364
CAS Number7722-64-7
EC Number231-760-3
Merck Number14,7655
PubChem Substance ID516875
Synonym PERMANGANIC ACID POTASSIUM SALT Permanganic acid, potassium salt Permanganate of potash diverseydiversolcxu Cairox KMnO4 Chameleon mineral POTASSIUM MANGANATE (VII) 高锰酸钾(药用) Condy's crystals Potassium (permanganate de) Kaliumpermanganat 高锰酸钾 Permanganic acid (HMnO3) potassium salt argucide Potassium permanganate chlorisol Permanganic acid potassium salt C.I. 77755 icc237disinfectant,sanitizer,destainer,anddeodorizer chameleonmineral BETZ 0263 POTASSIUM PERMANGANATE caswellnumber699 epapesticidechemicalcode068501 diverseydiversolcxwitharodyne ci77755 过锰酸钾 高锰酸钾标准溶液, 0.1N STANDARDIZED SOLUTION 灰锰氧,过锰酸钾 c.i.77755 Potassium manganate (KMnO4) Permanganate de potassium 高锰酸钾; 过锰酸钾 Permanganic acid (HMnO4), potassium salt cairox hilco#88 Pure Light E 2 Condy's crystals kaliumpermanganaat 高锰酸钾,溶液(0.1N) 灰锰氧 高锰酸钾 溶液 高锰酸钾, ACS, 99.0% MIN Insta-perm 過錳酸鉀 algae-k Manganese potassium oxide (KMnO4) KALII PERMANGANAS 高锰酸钾, LOW IN MERCURY, ACS, 99.0% MIN condy’scrystals 灰锰氧;过锰酸钾 Potassio (permanganato di) 高錳酸钾 POTASSIUM PERMANGANATE
Chemical Name Translation高锰酸钾
Wiswesser Line NotationKA MN-O4
InChIInChI=1S/K.Mn.4O/q+1;;;;;-1
GHS Symbol
TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human - woman
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Vascular - BP lowering not characterized in autonomic section
   Liver - hepatitis (hepatocellular necrosis), diffuse
   Kidney, Ureter, Bladder - changes in tubules (including acute renal failure,
   acute tubular necrosis)
REFERENCE :
   HETOEA Human & Experimental Toxicology.  (Macmillan Press Ltd., Brunel Road,
   Houndmills, Basingstoke, Hampshire, RG21 2XS, UK) V.9- 1990-
   Volume(issue)/page/year: 15,259,1996

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : 1151 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 36(9),15,1971

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 143 mg/kg
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - dyspnea
   Gastrointestinal - other changes
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,493,1969

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Mammal - dog
DOSE/DURATION           : 400 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YKYUA6 Yakkyoku.  Pharmacy.  (Nanzando, 4-1-11, Yushima, Bunkyo-ku, Tokyo,
   Japan)  V.1-    1950-  Volume(issue)/page/year: 31,855,1980

TYPE OF TEST

{hazard_

{haz

TYPE OF TEST            : DNA repair
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 625 ug/well
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 133,161,1984

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Microorganism - not otherwise specified
DOSE/DURATION           : 10 ppm
REFERENCE :
   JOBAAY Journal of Bacteriology.  (American Soc. for Microbiology, 1913 I
   St., NW, Washington, DC 20006)  V.1-    1916-  Volume(issue)/page/year:
   54,767,1947

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 uL/tube
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 260,295,1991

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 200 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,95,1981

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - mouse Mammary gland
DOSE/DURATION           : 1 mmol/L/48H
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 67,221,1979

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 718 mg/kg/7D (Continuous)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 240,159,1990

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intratesticular
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 400 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - male fertility index (e.g. # males impregnating
   females per # males exposed to fertile nonpregnant females)
REFERENCE :
   FESTAS Fertility and Sterility.  (American Fertility Soc., 608 13th Ave. S,
   Birmingham, AL 35282) V.1-    1950-  Volume(issue)/page/year: 24,884,1973

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Intratesticular
SPECIES OBSERVED        : Rodent - gerbil
DOSE                    : 25 mg/kg
SEX/DURATION            : male 1 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - male fertility index (e.g. # males impregnating
   females per # males exposed to fertile nonpregnant females)
REFERENCE :
   IJEBA6 Indian Journal of Experimental Biology.  (Publications & Information
   Directorate, CSIR, Hillside Rd., New Delhi 110 012, India)  V.1-    1963-
   Volume(issue)/page/year: 14,617,1976

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 513 mg/kg
SEX/DURATION            : male 5 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - spermatogenesis (incl. genetic material,
   sperm morphology, motility, and count)
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 240,159,1990

Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
    Hazard statements
    • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
    • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
    • H302 Harmful if swallowed 吞食有害
      WGK Germany2
      Personal Protective Equipment Eyeshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US) dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Faceshields, Gloves, half-mask respirator (US), multi-purpose combination respirator cartridge (US)
      RTECSSD6475000
      Safety Statements
      • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
      • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
        UN Number UN1490 1490/1482 UN 3082 9/PG 3
        Risk Statements
        • R52/53
        • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
        • R51/53
        • R50/53
        • R22 Harmful if swallowed 吞咽有害
          Storage condition Light Sensitive 密封保存。 Store at RT.
          Hazard Codes O,N O;Xn;N N O,Xn,N
          Signal word Danger Warning
          Packing GroupII
          Hazard Class5.1
          Restrict 易制毒化学品
          Restrict 易制爆危险化学品
          Warnings 危化品目录(2015)
        • 氧化剂,消毒剂,有机合成,净水。容量分析氧化还原法测定用试剂。色谱分析用试剂。用于发射光谱分析。点滴分析钡、银、硫酸盐、铁、钒及锡,临床脱落细胞检验等。
        • {ALF} The oxidizing power of permanganate can be varied according to the pH of the reaction medium, the use of co-reagents, phase-transfer catalysis, etc. For a comprehensive review of permanganate oxidations in organic chemistry, with particular emphasis on novel applications, see: Synthesis, 85, (1987).
        • {ALF} For phase-transfer oxidation, catalyzed by Tetra-n-butyl­ammonium hydrogen sulfate, A14047, of unfunctionalized benzylic methylenes, or benzylic alcohols to carbonyls, see: Synthesis, 915 (1987). Similar transformations have been carried out in the presence of triethylamine: Synthesis, 293 (1989).
        • {ALF} In combination with CuSO 4, has been used as a reagent for the heterogeneous oxidative cyclization of the primary position of a primary-secondary diol to the lactone: J. Chem. Soc., Chem. Commun., 634 (1988); Org, Synth. Coll., 9, 462 (1998):
        • {ALD} Merck: 14,7655
        • {ALF} For phase-transfer assisted oxidation of primary amines to azo compounds, see: Bull. Soc. Chim. Belg., 102, 59 (1993).
        • {ALFA} In combination with TMS chloride
        • {ALF} Classical permanganate cleavage of olefins is difficult to control, and normally proceeds to the highest possible oxidation level. Adsorption of the reagent on moist alumina has been found to attenuate its activity and allow good yields of aldehydes to be obtained. This would appear to provide a possible alternative to ozonolysis for this conversion: J. Org. Chem., 58, 2918 (1993). For use in the cis-hydroxylation of olefins, see Dicyclohexano-18-crown-6, A15344.
        • {ALF} For the use of (1-Hexadecyl)­trimethyl­ammonium bromide, A15235, as a surfactant in permanganate oxidations in micelles, see: Can. J. Chem., 67, 1381 (1989).
        • {ALF} In combinat
        • 7722-64-7 PO03351000 Potassium permanganate, solution 0,2 mol/l (1 N)	高锰酸钾滴定液,0.2mol/l

          化学属性

          Mol. FormulaKMnO4
          Mol. Weight158.03
          Density1 g/mL at 25 °C
          Melting Point240° dec.
          TSCAYes
          SolubilityPartially soluble in water. Decomposes in organic solvents and acids
          Stability对湿度敏感
          Appearance solution (volumetric)